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Batteries are still the weak link in any off-the-grid system; wether one goes with the "cheap" golf cart ones [which last 5 years] or buys more expensive ones [with 20 year life expectancy], they still cost too much for too little life. In the last 10 years there have been some new developments but at present good old lead-acid batteries are still the most sensible choice. At least their recycling rate is around 99%, so their environmental impact is low.
The most important source of electricity in the off-grid situation, however, is the vast amount NOT used due to ultra-efficient appliances.
Wether it is a lightbulb, a washing mashine, a well pump, a fridge or freezer etc., it is usually possible to find one that is three to four times more efficient than mainstream technology; while these efficient appliances tend to cost more initially they will also last a lot longer and thereby pay for themselves.
My home-built fridge uses all of 60 watts when it runs and it is on roughly 20% of the time; a comparable store-bought one easily uses TEN [!] times more while doing the same job. The technology is already here, it just is not marketed.
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